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Activesync uses TCP/IP to communicate with the Axim. I would look at the differences between the network at home and the network at work in how IP numbers are assigned to the devices attached. A/S identifies your Axim by the IP number and name. It can flex on the IP number, to accomodate DHCP, but once it pairs up a partnership with an IP number, if that IP number changes and A/S hasn't seen a "disconnect" from the old IP number it won't let you connect to the partnership and defaults to Guest.
There may also be firewall differences between home and work that are confounding the activesync connection process.
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