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There are ways to decrypt iTunes AAC files (maybe podcasts? I dont know what format they are in) to m4a files and then play those files on a PPC without having to convert them to mp3 or some other format and lose sound quality. Dont bother asking me how since doing so may be illegal. But the internet is a wonderful thing, chock-full of information...
As for TV shows...those are DRMed also and to my knowledge there are no programs (yet) that are capable of decrypting them.
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