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I'm not sure if this directly addresses your problem or not, but it might give you some ideas.
Open the Control Panel on your PC, then select mail, then show profiles. Do you have two profiles (one for the company and one that you created yourself)? If so, you can select your personal one as the default when Outlook opens. Or, you can have it prompt you for which profile to open when opening Outlook. If not, maybe you can create a new profile and point it to the pst that you made yourself.
At my work, I have a Groupwise server and then an Outlook profile that I created myself. When viewing profiles, it's pretty obvious which is which but it might not be so easy with two Outlook profiles.
Since I handle mail separately, I have no need for Outlook to read any data off the server (the address book on the server is so large that I would never want it all on my Pocket PC).
Not sure why, but ActiveSync somehow knows that I only want to sync the info. in my personal profile. Maybe if the company profile was the default, it would sync that data.
Just some ideas to go on . . .
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