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Having multiple profiles should not be a problem as long as the profile is configured properly for the person that is logged in.
I have done a quick lookup and it seems that your mapi32.dll may be wrong or corrupted. This file is located in your Windows\System folder. This file is updated when either you upgrade Office or add a Service Pack. Sometimes, this file is not updated properly. Here is the fix:
RESOLUTION
To resolve this problem:
In Outlook, click Detect and Repair on the Help menu, and then click Start.
Disconnect the Windows CE-based device from the computer, and then quit Outlook. Test to determine if the problem is resolved, and if not, continue to the next steps.
Click Start, point to Find and then click Files or Folders.
In the Named box, type mapi32.dll, click My Computer in the Look In box, and then click Find Now.
Right-click the Mapi32.dll file, click Rename, type mapi32.old, and then press ENTER to accept the name change. Note that if there are multiple copies of the Mapi32.dll file in the list, rename each file to a unique name.
Quit the Find tool, and then start Outlook.
When Outlook starts and you receive a prompt that files are missing, click Yes to permit the Windows Installer to replace them.
Reconnect the Windows CE device to the desktop computer and attempt to synchronize.
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