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I assume that by "word" you mean Microsoft Word 6 or 2002, though the answer is the same for any word processing software.
There are some <expensive> enterprise solutions that allow reconversion of Adobe pdf files; none that I know of that allow reconversion of Microsoft Reader *.lit files.
The question is one of copyright protection; if your only copy of something you yourself did is in one of these formats, and you want to modify it, and (to emphasize) you are the copyright holder, then you probably gave yourself printing privileges, can print out your file, run it through a scanner and OCR software, and have it back in MS Word or whatever word processor.
Since both Adobe and MS Reader, as well as my favorite, Mobipocket, allow bookmarking and annotation, why would you want to change formats?
If you have Adobe Acrobat, you have even more ways to deal with *.pdf files.
Again, why do you want to? Is it fair use of copyrighted materials, or something else?
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