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I do this. You have to first create a partnership in ActiveSync on the work PC by connecting the Axim directly to it. Once that partnership is created, you can select which PC to sync with by going into ActiveSync on the Axim and tapping on "Tools" at the bottom left, then tap on "Options". In the bottom select box you can select from all PC's that you have created partnerships with.
VPN into your work network and select your work PC from the list and it will sync with it from anywhere in the world via the internet.
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